![]() ![]() Choice c illustrates Hund’s rule (named after the German physicist Friedrich H. ![]() Similarly, experiments have shown that choice b is slightly higher in energy (less stable) than choice c because electrons in degenerate orbitals prefer to line up with their spins parallel thus, we can eliminate choice b. Figure 6.29 tells us that the next lowest energy orbital is 2 s, so the orbital diagram for lithium isīecause of electron-electron repulsions, it is more favorable energetically for an electron to be in an unoccupied orbital than in one that is already occupied hence we can eliminate choice a. We know that the 1 s orbital can hold two of the electrons with their spins paired. The next element is lithium, with Z = 3 and three electrons in the neutral atom. Otherwise, our configuration would violate the Pauli principle. Written as 1 s 2, where the superscript 2 implies the pairing of spins. The orbital diagram for the helium atom is therefore From the Pauli exclusion principle, we know that an orbital can contain two electrons with opposite spin, so we place the second electron in the same orbital as the first but pointing down, so that the electrons are paired. We place one electron in the orbital that is lowest in energy, the 1 s orbital. For hydrogen, therefore, the single electron is placed in the 1 s orbital, and the electron configuration (also known a spdf notation) is written as 1 s 1 and read as “one-s-one.”Ī neutral helium atom, with an atomic number of 2 ( Z = 2), has two electrons. Here is a schematic orbital box diagram for a hydrogen atom in its ground state:įrom the orbital diagram, we can write the electron configuration in an abbreviated form in which the occupied orbitals are identified by their principal quantum number n and their value of l ( s, p, d, or f), with the number of electrons in the subshell indicated by a superscript. A filled orbital is indicated by ↑↓, in which the electron spins are said to be paired. That is, recognizing that each orbital can hold two electrons, one with spin up ↑, corresponding to m s = +½, which is arbitrarily written first, and one with spin down ↓, corresponding to m s = −½. First we determine the number of electrons in the atom then we add electrons one at a time to the lowest-energy orbital available without violating the Pauli Exclusion Principle. We write electronic configurations by following the aufbau principle (from German, meaning “building up”). The periodic table is an incredibly helpful tool in writing electron configurations. ![]() Using the periodic table to determine the electron configurations of atoms is key, but also keep in mind that there are certain rules to follow when assigning electrons to different orbitals. Recall, we can use the periodic table to rank the energy levels of various orbitals. The valence electrons, electrons in the outermost shell, are the determining factor for the unique chemistry of the element. Many of the physical and chemical properties of elements can be correlated to their unique electron configurations. Commonly, the electron configuration is used to describe the orbitals of an atom in its ground state, but it can also be used to represent an atom that has ionized into a cation or anion by compensating for the loss of or gain of electrons in their subsequent orbitals (we will examine those in the next section). The electron configuration of an atom is the representation of the arrangement of electrons distributed among the orbital shells and subshells. ![]()
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![]() ![]() And if she isn't careful, she might be its final victim. Could all these events be connected? As Deirdre digs deeper into the past, she becomes increasingly convinced that her father's death is merely the deadly third act in a story that has long been in development. Deirdre was at the Nichols' house the night of the murder, which was also the night she suffered her own personal tragedy. ![]() ![]() Back in 1963, Joelen confessed to killing her movie-star mother's boyfriend. Overview Finalist for the Mary Higgins Clark Award From the award-winning author of There Was an Old Woman comes a riveting tale of domestic noir, infused with old Hollywood folklore and glamour, set in a town rife with egotism and backstabbing and where fame and infamy are often interchangeable. The sudden resurfacing of Deirdre's childhood BFF Joelen Nichol - daughter of the famous and infamous Elenor "Bunny" Nichol - seems like more than a coincidence. But the longer she stays in town, the more Deirdre begins to suspect that everything isn't as open-and-closed as she first presumed. At first, Deirdre assumes her father's death was a tragic accident. In a cruel Sunset Boulevard twist, Deirdre arrives home to find her father facedown in his too-small swimming pool - dead. Night Night, Sleep Tight finalist for the mary higgins clark awardfrom the award-winning author of there was an old woman comes a riveting tale of domestic. But she gets a lot more than she expected. When Deirdre Unger makes the drive from San Diego to Beverly Hills to help her father put his dilapidated house on the market, she's expecting to deal with his usual kvetching and dark moods. ![]() ![]() If you want learn more about it, then head over to the excellent Wiki article at Ripping games at Emulation General Wiki. Sharing is not allowed, but you can make backups and play them on any emulator you like. This will create the ROMs you can usually download from other places, but these are your own. If you have the hardware, software and knowledge, then you can start dumping your own private collection.
![]() ![]() Apollo programme (Missions 15, 16, and 17) during 19. The automaker's subsidiary GM Defense LLC "is on the front end" of this, Ryder said, "because it's a government opportunity, but we have reached back into the the full scale and scope of GM engineering, R&D and the capabilities of the broader corporation, so this is very much a one-team GM effort.As the Moon landings progressed Dinky reflected the interest in space and produced the 355 Lunar Rover Vehicle based on NASA’s Lunar Roving Vehicle (LRV) which was a battery-powered four-wheeled rover used on the Moon during the last three missions of the U.S.A. The companies didn't specify an investment amount. some of that we'll pull off the shelf and the rest as a team we're gonna figure out how to get it done." ![]() When asked if the vehicle will be based off an existing GM product, Jeff Ryder, vice president of growth and strategy at GM Defense, said: "This is a more ambitious vision for lunar habitation and mobility. "Really the capabilities of the vehicle are still in formulation," he said, adding that Lockheed and GM teams are "making great inroads on electrification and autonomy and vehicle concepts and our experts are leveraging all our experience in building landers and building deep space probes to come up with vehicles that will meet what we need to do." Kirk Shireman, vice president of lunar exploration campaigns at Lockheed, said the vehicle will be made of "very lightweight, very strong and resilient materials." Lockheed and GM are in the early stages of development but plan for the LTV to be an electric vehicle since combustion engines cannot be used on the moon, Wexler said. NASA may publish a formal request for proposals from American companies to develop the LTV at a later date." "Additionally, NASA plans to hold an industry day later this year to provide the community with updated LTV (lunar terrain vehicle) information and enable commercial readiness for this endeavor. Last year, NASA issued two requests for lunar mobility approaches and commercial concepts, and those "responses provide NASA valuable insight to shape a lunar surface mobility plan and inform a potential future acquisition strategy," the federal space agency said in a statement to The Detroit News on Wednesday. "The potential for what we're producing with Lockheed will help drive science, innovation and technology forward exponentially we believe for all of humankind," said Alan Wexler, senior vice president of innovation and growth at GM, during the media call. These next-generation lunar vehicles will be designed to travel longer distances to get to the moon’s south pole, which is colder, darker and has more rugged terrain. They plan to produce "a unique vehicle with innovative capabilities, drawing on their unparalleled engineering, performance, technology and reliability legacies," the companies said in a joint press release. GM will bring its knowledge of battery-electric and autonomous vehicle technologies to the table for the development. Lockheed Martin, which has more than 50 years of experience in working with NASA, will lead the team. "This partnership is really about getting ahead of NASA's future procurements that they may have and really looking at the commercial environment that's going to be on the lunar surface and building this partnership in advance of that, so that we can lead the way in mobility on the moon," said Lisa Callahan, vice president and general manager of commercial civil space at Lockheed Martin, on a call with media Wednesday. The companies expect a request for proposals to come later this year. NASA has asked industry leaders to send ideas for lunar rovers and for a new lunar terrain vehicle, or LTV, for its Artemis program, which is working to get astronauts back on the moon. ![]() is partnering with Lockheed Martin, a security and aerospace company, to develop lunar vehicles to potentially carry astronauts on the moon, the companies said Wednesday. ![]() ![]() ![]() If the weather is too hot/cold or inclement, students can observe from the windows of the classroom. Each student should have a journal to capture these notes. Take students outside to make observations about their surroundings. Demonstrate for students how to use their senses to make observations about nature.For example, the metal chair legs feel cold. Now ask the students to describe the object using their senses. Review the five senses: sight, smell, taste, touch, and hearing.Ask students to think of words to describe the object. Display an object from around the classroom (book, crayon, eraser, chair, etc.). ![]() ![]() Modify handouts and give preferential seating for visual presentations. Students should be familiar with making observations and painting styles. This lesson works in general content area classes and art classes. Teachers should plan for places to observe nature with students. Artist Statement: Painting Nature Scenes.Check out Sharing Tips or Instructional Benefits when implementing Google Docs and Google Slides with students. Recommended Student MaterialsĮditable Documents : Before sharing these resources with students, you must first save them to your Google account by opening them, and selecting “Make a copy” from the File menu. ELA-LITERACY.W.3.2 Write informative/explanatory texts to examine a topic and convey ideas and information clearly.ĮLA-LITERACY.W.4.2 Write informative/explanatory texts to examine a topic and convey ideas and information clearly.ĮLA-LITERACY.W.5.2 Write informative/explanatory texts to examine a topic and convey ideas and information clearly. ![]() ![]() ![]() – If you have a vac ban then you won’t able to play online games, create a new account if the account you gonna use have one of those. To run this game with admin privileges instead Check the price history, create a price alert, buy games. – If you install games to your system drive, it may be necessary Compare prices of over 40 stores to find best deals for Baldurs Gate 3 in digital distribution. – Turn Off your AntiVirus and Block the game’s exe in your firewall to prevent the game from – Do not block the game with firewall if you are playing an online game with your friends. – In the case of an offline game, you may need to block it with firewall to prevent it from going online. – It is recommended to turn off your antivirus as some files get detected as false positive. Windows Key + R and type (steam://install/480). Modes : MultiPlayer ❌ | Co-oP Fix By: OnlineFix General Notes: ĥ) In-game -> Connection: Accept an invitation from a friend Creating a server : Multiplayer -> Create a -> Changing the parameter Who can join? on Invitees -> + -> invite friends and look forward to their connection.! The minimum requirements might decrease over the course of Early Access, as performance improves.ġ) Download the game using a Torrent program or Direct programĢ) Extract the game to your preferred location with WinRar or 7-ZipĤ) No need to install the game, just start with the LAUNCHER of the game as administratorĢ) Copy the content of this crack to your game folderĤ) Launch the game via bin\bg3.exe or bin\bg3_dx11.exe. Additional Notes: Default API is Vulkan 1.1. ![]() ![]() Graphics: Nvidia GTX 780 / AMD Radeon R9 280X.Requires a 64-bit processor and operating system.Baldurs Gate 3 Trainer 4.1.106. These Baldur's Gate 3 cheats are designed to enhance your experience with the game. I think it must have something to do with the fact that there is a secondary launcher that opens up between launching the game from the steam library and the actual program booting up. Gather your party, and return to the Forgotten Realms in a tale of fellowship and betrayal, sacrifice and survival, and the lure of absolute power. Our Baldur's Gate 3 +15 trainer is now available for version 4.1.106.9344 and supports STEAM, GOG. Problems with Baldurs Gate 3 and Steam Controller Ive tried everything I can think of to get the steam controller running with BG3. ![]() ![]() ![]() Hipshot Ultralights and Gotoh tuners come in both bass side and treble side. The 3/8″ size is common for modern instruments with smaller tuners. More information on measuring your tuner’sġ/2″ is for the larger size found on many vintage instruments, Fenders, and Fender clones. a 1/2″ tuner will measure roughty 3/4″ across.a 3/8″ tuner will measure roughly 9/16″ across.We are looking for the distance from one side of the nut to the other parallel side Measure the nut that secures the tuner to the headstock.a 1/2″ tuner will have a hole that is 11/16″ in diameter.a 3/8″ tuner will have a hole that is 9/16″ in diameter.Remove a tuner and measure the hole that was drilled in the headstock.To determine what size is right for your bass, follow one of these two easy steps: Hipshot Vintage tuners have 1/2″ posts, Hipshot Ultralight tuners come in both 1/2″ and 3/8″ sizes, and Gotoh tuners have 3/8″ posts. It’s simple math: 5 Ultralights weigh the same amount as 4 Gotoh tuners. When your bass has 5 or more strings I recommend using the Hipshot Ultralights to save on weight. If you’re not using a Fender bass, many other basses use a smaller type of tuner which can be replaced by a Gotoh or Hipshot Ultralight tuner. Get a Hipshot Vintage Tuner to keep her looking sharp. Note: Fender style basses with vintage tuners can also be upgraded with Ultralight tuners, but Ultralight tuners are much smaller in design and will not cover all of the screwholes from the previous tuner. If you cannot figure out which style to use, call me up or email me to ensure you’re not ordering the wrong part. I recommend looking at the back of your headstock and comparing the shape of your tuner to the Vintage tuner shapes on our website or by looking at this diagram. If you decide to use Hipshot’s Ultralight tuners, you can also shed some weight at your headstock which decreases neck dive.īefore you change your tuner, you first have to find which replacement will work for your bass.įender basses use tuners which normally can be replaced by a Hipshot Vintage Tuner model, although some models are designed for an Ultralight tuner model. Although they are a minor improvement, upgrading your current bass tuners is a great way to increase tuning stability and a quick way to change the aesthetic of your bass. Here in the shop we receive a lot of questions on tuners including how upgrading from stock tuners makes a difference and then subsequently, how to change them. Written by Evan, Best Bass Gear’s Prewire & Tech Support (Electronics and Hardware) Similarly, please send any comments or critiques to the moderators.Tuners: What Kind to Buy & How to Install Them (with Pictures) We encourage you to report spam posts or posts that violate the rules, but please send a message to the moderators at the same time. ![]() Please tag video or audio of you or your band with in the subject line of the post. Requests for tab should be made in /r/basstabs and will be removed from /r/bass ![]() Resist the urge to start "gig pic" "bass face" and "family photo" threads. Also, do not post links to giveaways where you personally benefit (getting more entries) by propagating (spamming) a link. Posts made outside of the thread will be removed and asked to be reposted.ĭon't use the sub to sell or advertise your gear (with very few exceptions, ask the mods). New Bass Day (NBD) and Gear posts go into the weekly threads. We have lots of common questions with lots of common answers. Previous AMAs FAQ and Wiki Bass Resources 2016 Official Pedals Thread Follow /r/bass on Twitter Related Communities Other InstrumentsĬheck the sidebar, the FAQ, and search for your answer before making a post. ![]() ![]() ![]() Motorcycles and mopeds are unaffected by LEZ schemes in Scotland.Ĭertain vehicle types are also exempt from LEZ emission requirements in Scotland - these are set out below: If you are thinking of switching to electric, you might be eligible for a grant or loan to help you buy - see the Energy Saving Trust website for more information. Use the Transport Scotland's vehicle registration checker to see if your vehicle will comply.įully electric vehicles comply with LEZ requirements in Scotland. They are consistent with similar schemes across the UK and Europe.įor practical purposes, it is generally the case that diesel engine vehicles registered after September 2015, and petrol vehicles registered from 2006 onwards will meet the required LEZ standards. Buses and HGVs from 2013 onwards also generally meet the Euro 6 standard. These standards were publicly consulted on in 20/20 and confirmed through the Transport (Scotland) Act 2019 and subsequent regulations. Euro VI for heavy duty diesel vehicles such as buses/coaches and HGVs.Euro IV for heavy duty petrol vehicles such as buses/coaches and HGVs.The M8 motorway is not included within Glasgow's LEZ.Ĭlick on the links below, for further details about specific roads/streets affected by Glasgow's LEZ:Įmission standards/Vehicle Registration CheckerĮmission standards for LEZs in Scotland have been set in leglislation at national level - these are: It covers an area of the city centre bounded by the M8 motorway to the north and west, the River Clyde to the south and Saltmarket/High Street to the east. Glasgow's LEZ is approximately one square mile in size. Enforcement for vehicles registered to a residential property within the zone area will start on 1 June 2024 (see section below on Zone Residents for more details).Phase 2 (all vehicles) came into force on 1 June 2023.Phase 1 (buses only) was introduced on 31 December 2018.Glasgow's LEZ is being phased in to give everyone time to prepare: ![]() You can read the full details of Glasgow's LEZ Final Scheme Design by clicking on this link.
![]() ![]() It goes from being quite light in color to a deeper brown, a bit more like the cookies as baked. In fact, even the color of the dough seems to change color a bit as the dough rests. The texture of the baked cookies is really amazing after the wait. Ive tried baking the dough right away, and baking it after chilling it for at least a full day. The dough really does benefit from being chilled for 24 to 72 hours. Note: There is a daily limit on the number of passes. Once it has expired, you can log in again to get a new pass.
![]() Be sure to do the steps listed above if you intend to play with more than four people. ![]() Sometimes crashes just happen, and they’re not really something you can bet on happening. If all is well, keep adding mods until you find the source of your problems. This should provide a clean mod save folder. Start the game then exit at the main menu without starting any characters. Repeat step 2 (with the additional mod) and 3. Try deleting the mod save folder while the mod launcher is on screen.I've tried deleting the localsettings file a number of times before loading the mod changes. I've tried to load a handful of different mods and/or mod packs, but I get the same result. If there are no crashes, exit the game and boot with both SynergiesMOD and another mod. Sometimes it crashes just before giving me a character selection screen.Both of you enter and exit the same map at the same time around 4 or 5 times.Have a friend join your game, with only SynergiesMOD enabled.Boot the game only with SynergiesMOD enabled.Solving your crashing issues can be complicated, but the easiest way is to boot the game with a single mod, test it in multiplayer action, then relaunch with two mods and so on. Since I’ve been poking around with so many mods, I’ve had more crashes in Torchlight 2 than I have had with any other game in the past few years. 1 DrunkSturj 8:52am Originally posted by steffire3: Try deleting the mod save folder while the mod launcher is on screen. If you cannot see your friend’s game, double-check your mod list and relaunch.Your client will restart and you should be able to join with no problem. The wrench icon syncs your client to the host’s mods so there are no compatibility issues during play. If there is no “Join” option when you click on a game, look at the top of your screen for a small wrench icon.If there are still no results, double-check that you both have the same mods and that they are in the same order. If there is no option to show your contact’s game, search for the game name.If you do not see their game on the list, click on their name and then “Show Game”. Ensure the host’s Runic account is on your contact list in-game.Joining a game with friends is much easier than finding a compatible pub, but it is not as simple as with vanilla Torchlight 2. Finding games with the right combination of mods can be difficult, to say the least. Finding public games with mods you’re interested in playing with requires choosing mod collections at the top of the internet lobby and seeing what is available. Joining your friends’ games and joining pub games are entirely different ballparks due to the mod list and order system. Sometimes these recommendations will be found in the comments section, and sometimes they are found in the mod loader. Be sure to read the mod’s page on the Steam Workshop to see if the author recommends a particular placement. Some mods do not require that they be in any particular position, but some do. ![]() Make sure that everyone launches the game with mods and not the vanilla client.Make a list of mods to give anyone joining your game and give the priority order to avoid compatibility issues.I was looking at a list of mods since I've heard that the game is pretty easy to mod. I've had success in all three of my classes, and I want to branch out. Everyone will have to sync to the host when they try to join a game, but you can iron out several connectivity kinks by having everyone download each mod before they launch the game. 9 days ago Torchlight 2 Mods For the time being, I'm holding off Diablo 2 because I'm sick of how easily Diablo kicks my butt, and I'm considering returning to Torchlight.If you don’t have a moderately strong computer, you might have no choice but to skip this one. All I get is a little angelwing notification in the corner that it has crashed. Additionally, this mod may kill a lot of players’ framerate, because you’ll often run into literal hordes of enemies ranging in the dozens, which, unless you have a crazy powerful computer, is going to bring the game to a halt at times. However, this mod may be problematic for some, because it makes the game quite a bit harder, being balanced around the harder difficulties. Of all the mods on this list, this is objectively the most important, because without it you’re missing out on a lot of crazy cool content. In addition to three new classes, the mod adds new towns, new dungeons, and even revamps new game plus, adding new content to the higher tiers of playthroughs, such as unique legendary weapons, new awesome looking armors, and even new bosses. ![]() The Synergies mod might as well be considered an expansion pack for the game, considering it adds a ludicrous amount of original content while also reworking vanilla content. This is probably the most important mod on this list, because it is enormous. ![]() |
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